Asymmetric synthesis of ageliferin.
نویسندگان
چکیده
We describe herein an asymmetric synthesis of ageliferin. A Mn(III)-mediated oxidative radical cyclization reaction was used as the key step to construct the core skeleton of this pyrrole-imidazole dimer. This approach resembles the biogenic [4 + 2] dimerization in an intramolecular fashion.
منابع مشابه
Total Synthesis of Ageliferin via Acyl N-amidinyliminium Ion Rearrangement.
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 133 39 شماره
صفحات -
تاریخ انتشار 2011